
(a) Mapping of Na acquired using time-of-flight secondary ion mass spectrometry (ToF-SIMS) showing Na accumulating on edges of MoS2 monolayer flakes.
(b) DFT calculations of the strain correlated with the number of Na atoms on edge, indicating Na atoms at the edge can notably relax the strain for small crystals.
(c) Illustration of lattice shrinkage induced by Na adsorption at the monolayer flake edges.
(b) DFT calculations of the strain correlated with the number of Na atoms on edge, indicating Na atoms at the edge can notably relax the strain for small crystals.
(c) Illustration of lattice shrinkage induced by Na adsorption at the monolayer flake edges.
Scientific Achievement
A new surfactant-mediated growth mechanism was discovered that enables deterministic growth of large area 2D crystals.
Significance and Impact
The surfactant-mediated growth of 2D crystals enables the lithography-free, patterned growth of 2D materials for atomically thin electronic devices with desirable configurations.