Abstract
Recent studies have reported the existence of an epitaxially-stabilized
tetragonal-like (`T-like') monoclinic phase in BiFeO3 thin-films with high levels of compressive strain. Though there is abundant evidence that structural and ferroelectric properties are di®erent
than in rhombohedral-like (`R-like') films with lower levels of strain, little information exists
on magnetic properties. Here,we report a detailed neutron scattering study of a nearly phase-pure film of T-like BiFeO3. By tracking the temperature dependence and relative intensity of several
superstructure peaks in the reciprocal lattice cell, we confirm antiferromagnetism with largely G-type character and T_N = 324 K. A minority magnetic phase with C-type character is also reported with T_N= 260 K. The co-existence of the two phases in T-like BiFeO3 and the difference in ordering
temperatures between R-like and T-like systems is explained through simple Fe-O-Fe bond distance
considerations.
