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Incommensurate Charge Order Phase in Fe2OBO3 due to Geometrical Frustration...

Publication Type
Journal
Journal Name
Physical Review Letters
Publication Date
Volume
99
Issue
25

The temperature dependence of charge order in Fe$_2$OBO$_3$ was
investigated by resistivity and differential scanning calorimetry
measurements, M\"ossbauer spectroscopy, and synchrotron x-ray
scattering, revealing an intermediate phase between room temperature
and $340\,{\rm K}$, characterized by coexisting mobile and immobile
carriers, and by incommensurate superstructure modulations with
temperature-dependent propagation vector $(\frac{1}{2},0,\tau)$. The
incommensurate modulations arise from specific anti-phase boundaries
with low energy cost due to geometrical charge frustration.