Polystyrene Glasses under Compression: Ductile and Brittle Responses

Polystyrene of different molecular weights and their binary mixtures are studied in terms of their various mechanical responses to uniaxial compression at different temperatures. PS of M_w = 25 kg/mol is completely brittle until it is above its glass transition temperature T_g. In contrast, upon incorporation of a high molecular weight component, PS mixtures turn from barely ductile a few degrees below its T_g to ductile over 40° below T_g. In the upper limit, a PS of M_w = 319 kg/mol yields and undergoes plastic flow, even at T = −70 °C. The observed dependence of mechanical responses on molecular weight and molecular weight distribution can be adequately rationalized by the idea that yielding and plastic compression are caused by chain networking.