The Electrolysis of Nitrogen Gas to Ammonia
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The Electrolysis of Nitrogen Gas to Ammonia

Top: carbon nanospikes act as a conduit for electrons to react with dissolved nitrogen gas in water, by creating high localized electric fields (green cloud). Bottom: transmission electron micrograph of carbon nanospikes.

A physical catalyst, similar to the one previously reported for the reduction of CO2 to ethanol, is used to electrochemically reduce nitrogen gas to ammonia at room temperature.

Y. Song, D. Johnson, R. Peng, D. K. Hensley, P. V. Bonnesen, L. Liang, J. Huang, F. Yang, F. Zhang, R. Qiao, A. P. Baddorf, T. J. Tschaplinski, N. L. Engle, M. C. Hatzell, Z. Wu, D. A. Cullen, H. M. Meyer, B. G. Sumpter and A. J. Rondinone, “A physical catalyst for the electrolysis of nitrogen to ammonia,” Science Advances 4, 4 (2018). DOI: 10.1126/sciadv.1700336


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