Chemical and Morphological Changes of High Voltage Lithium-Manganese Rich Cathodes with Cycling
August 26, 2014 — Researchers used full-field transmission X-ray microscopy (TXM), capable of 3D imaging at high spatial resolution over a field of view of about 30×30×30 μm, to study the mechanisms driving structural degradation and voltage fade in a high capacity cathode material with nominal composition Li1.2Mn0.525Ni0.175Co0.1O2.
Direct observation of ferroelectric field effect and oxygen vacancy screening at ferroelectric–metal interface
August 21, 2014 — Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) studies of ferroelectric–metal interfaces revealed two distinct polarization charge screening mechanisms, with oxygen vacancies compensating negative charge and electrons compensating positive charge.
Magnetic fluctuations are good for superconductivity
August 15, 2014 — Atomic scale measurements of the strength of the magnetic fluctuations in a series of iron-based superconductors were made using high- resolution electron spectroscopy. Surprisingly, the superconducting transition temperature was higher when the magnitude of the fluctuating iron magnetic moment or “spin” was larger.
Thermopower Enhancement in Designer Oxide Superlattices
August 12, 2014 — A layer-by-layer design of 2D oxide superlattices with precisely controlled interface compositions has improved the thermopower of oxide thermoelectrics by 300% compared to that of bulk counterparts. Controlling the 2D carrier density through a new materials design strategy is critical for developing highly efficient thermoelectrics.
Structure-dependent Properties Guide Catalyst Design for Oxygenates Conversion
August 06, 2014 — The catalytic transformation of oxygenates (i.e. aldehydes, alcohols, ketones) on metal oxides to generate value added products such as fuels and additives is of great importance industrially, yet is not well-understood. ORNL researchers have provided new insights into how oxygenates react on metal oxide particles with well-defined structures.