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ORNL is well positioned to be a national leader in carbon management research.

Managing Carbon:
ORNL's Research Roles

In 1968 Jerry Olson, an ORNL ecologist, began studying how trees take carbon from the atmosphere, incorporate it into their leaves and wood, and return it as carbon dioxide after they die. Ever since, studies of the global carbon cycle have been under way at ORNL.

In 1975, a former ORNL director and nuclear power enthusiast, Alvin Weinberg, met with a number of government officials. He reiterated the scientific concern expressed by Roger Revelle of Harvard University in 1965. Weinberg told them that the carbon dioxide buildup in the atmosphere as a result of increased fossil fuel combustion for power production could lead to climate change. He reminded them that nuclear power plants do not produce carbon dioxide, a greenhouse gas that traps excess heat from the sun, warming the earth's surface. As a result, the effect of human activities on atmospheric carbon dioxide levels began to receive government attention; a carbon dioxide effects office was established in the Energy Research and Development Administration, the predecessor of the Department of Energy.

Habitat for Humanity demonstration (jpg, 37K)
Jeff Christian, director of DOE's Buildings Technology Center User Facility, shows a sample of polystyrene wall insulation that cuts energy use in a new Habitat for Humanity home.

Also in 1975, a program of carbon dioxide research was started at the Laboratory, which for years had focused on the development of nuclear reactors as power sources. During the same decade, because of the rising price of imported oil and concerns about nuclear reactor safety, ORNL researchers received funding to develop ways to use energy more efficiently and explore alternative, non-nuclear energy sources such as solar power, hydrogen, and fuels from biomass. As a result, ORNL researchers have developed insulation standards and more efficient refrigerators and heat pumps (for cooling homes and heating water) and have led a program that could bring large-scale production of biofuels from hybrid poplar trees and switchgrass.

From 1976 to 1984, Weinberg's Institute for Energy Analysis (IEA) in Oak Ridge was the nation's center for issues related to carbon dioxide. Then emerging studies of carbon dioxide and global climate at ORNL and other labs began receiving increased support from DOE, and IEA researchers such as Gregg Marland and David Reister came to ORNL. In 1989 ORNL Director Alvin Trivelpiece established the Center for Global Environmental Studies at the Laboratory.

Marilyn Brown (jpg, 34K)
Marilyn Brown has studied ways to control the greenhouse effect.

In 1997 a group co-led by Marilyn Brown, deputy director of the Energy Efficiency and Renewable Energy Program at ORNL, completed a report entitled Scenarios of U.S. Carbon Reductions, which involved contributions from five Department of Energy national laboratories. This report identified a portfolio of energy-efficient and low-carbon technologies that could provide a low-cost path for reducing carbon emissions in the United States to their 1990 levels by the year 2010. In 1999 the same five labs were asked to extend their analysis to 2020 and to identify specific policies and programs that could produce the technological advances and market penetration levels needed to address a range of energy and environmental challenges facing the nation. This follow-on study, Scenarios for a Clean Energy Future, is expected to be published later this year.

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Covers of Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions and Carbon Sequestration Research and Development, two DOE reports that ORNL played a major role in writing, editing, and publishing.

On Earth Day, April 24, 1998, DOE released a two-volume report entitled Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions. ORNL's David Reichle, Marilyn Brown, John Sheffield, and Mike Farrell were the technical co-leaders for the planning and drafting of the DOE report. The same year DOE organized a workshop to devise a roadmap for doing research on carbon sequestration, methods for capturing and securely storing carbon dioxide from fossil fuel plants. In December 1999 another DOE report, Carbon Sequestration Research and Development, was released; its technical co-leaders included ORNL's Reichle, Rod Judkins, and Gary Jacobs.

ORNL Emerging as Leader

Mike Farrell (jpg, 35K)
Mike Farrell examines a carbon management flow chart on the computer screen.

"For 25 years ORNL has been conducting research that positions us well to be a leader among DOE labs in carbon management," says Mike Farrell, director of ORNL's Global Environmental Studies Program and leader of the Laboratory's carbon management programs. "We have explored energy efficiency, clean energy, carbon sources and sinks, the global carbon cycle, biomass, and climate modeling.

"Because of our historically broad background in these areas, we were asked to co-lead the development of the greenhouse gas emission reduction and carbon sequestration reports. Doing this suite of reports allowed us to look at our own skills, other labs' capabilities, and available technologies related to carbon management."

Farrell defines carbon management as "the full range of science and technology opportunities (including policy options) to stabilize atmospheric CO2 concentrations by decreasing the carbon-production potential of the energy system and by reducing CO2 emissions, including the capture and sequestration of atmospheric CO2 and modification of the carbon biogeochemical cycle." The term "carbon management" has been adopted by the business community (e.g., electric utilities, coal mining firms, etc.) as preferable to "development of climate change technologies."

The carbon- and energy-related research being conducted at ORNL today is certainly no carbon copy of the type of research performed here in the past two-and-a-half decades. "What is new," says Farrell, "is research on carbon capture, emission reduction technologies, and sequestration."

One way to manage carbon is to use energy more efficiently to reduce our need for a major energy and carbon source—fossil fuel combustion. Another way is to increase our use of low-carbon fuels (natural gas and ethanol give off 40% as much carbon dioxide as coal when burned), and carbon-free fuels and technologies (nuclear power; hydrogen fuel cells; and renewable sources such as solar energy, wind power, and biomass fuels). Both approaches have long been studied by ORNL researchers and other DOE national laboratories.

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Mike Karnitz (left) and David Stinton chat in the High Temperature Materials Laboratory exhibit area during the Distributed Generation Showcase held June 19 and 20, 2000, at ORNL.

Today, for example, ORNL is studying distributed generation—electricity produced on site using fuel cells and microturbines (which operate on natural gas) and renewable energy systems such as wind turbines and solar electric cells to meet specific energy needs for factories, hospitals, and office and commercial buildings. ORNL researchers are devising better ways to combine microturbines with fuel cells, which provide waste heat that help run the turbines. According to Tony Schaffhauser, manager of ORNL's Energy Efficiency and Renewable Energy Program, microturbines could be combined with ORNL-developed heat pump chillers that may be marketed as air conditioners. If ORNL-developed desiccant systems are used to pull out the excess humidity, less air conditioning will be needed, decreasing energy use 15 to 20% and reducing carbon emissions. The desiccant material that absorbs moisture from the inside air before it is chilled will give it off to the outside air when the material is warmed by waste heat from a microturbine.

Measuring air flow in a microturbine (jpg, 43K)
Solomon Labinov prepares to measure air flow in a microturbine at ORNL's Buildings Technology Center while Jeff Christian looks on. The velometer Labinov is studying is next to the turbine, which drives the generator at right.

The third and newest way to manage carbon is carbon sequestration. In this proposed approach, carbon will be captured from the atmosphere and from stack emissions of fossil-fuel combustion facilities. Some of the carbon may be transformed into useful products. The rest will be transferred to aboveground terrestrial ecosystems such as forests, to belowground terrestrial ecosystems such as underground coal seams, and to the ocean.

DOE has established two carbon sequestration centers, one of which is co-led by ORNL researchers. It is the DOE Center for Research on Enhancing Carbon Sequestration in Terrestrial Ecosystems (CSiTE), and its co-manager is Gary Jacobs of ORNL's Environmental Sciences Division (ESD). (For details, see the "Capturing a Role in Carbon Storage Studies" article in the Review, Vol. 32, No. 3, 1999.) The other is the DOE Center for Research on Ocean Carbon Sequestration (DOCS). ORNL researchers David Cole (Chemical and Analytical Sciences Division) and Gerry Moline (ESD) participate in one of DOE's geologic sequestration projects.

In evaluating ORNL's emerging role as a leader in carbon management research, Farrell says, "We found that ORNL's missing pieces included analytical capabilities to determine the potential of geological and ocean systems to store pumped-in carbon, to predict how long it would be stored, and to assess if the sequestration methods are safe. We also need to determine the best mix of energy-producing technologies in terms of cost, energy production, and carbon dioxide emissions."

Carbon Management Model

Farrell and his colleagues see the need for a carbon management model, and they recently won internal funding to develop one. "We plan to build a carbon management model to evaluate different carbon management strategies and options," Farrell says. The team of ORNL researchers who have received funding to build the model are Tony King of ESD, Kathy Yuracko of the Life Sciences Division (LSD), Paul Leiby of the Energy Division, Mike Taylor of the Computational Physics and Engineering Division (CPED), and Brian Worley of the Computer Sciences and Mathematics Division (CSMD). They are conducting the research in collaboration with Pacific Northwest National Laboratory.

"We will be doing cost-benefit analyses of a mix of energy and sequestration technologies and predict their impacts on atmospheric carbon dioxide levels," says King, an expert in the global carbon cycle who will analyze natural impacts on carbon dioxide levels such as volcanoes, forest fires, and El Niño. "For example, we will compare terrestrial and ocean sequestration in terms of cost and the expected carbon storage time. We will analyze the risks of sequestration options and other carbon management strategies. We will do life cycle analysis and uncertainty analysis.

"Our model will update and combine existing global carbon cycle models, energy technology models, and economic models. The model will be modernized so that it can use different programming languages across platforms and make complex calculations on parallel supercomputers such as the IBM SP at ORNL."

"The model will be used to ask 'what if' questions," Farrell says. "For example, what if it was decided to introduce hydrogen fuel cell cars in the United States to greatly reduce carbon dioxide emissions from the transportation sector, which represents about one-third of total U.S. carbon emissions? What are the risks and uncertainties with respect to building an infrastructure to support these vehicles?"

In building such a model, the developers are following DOE assumptions, as explained by Farrell.

"We can reduce energy intensity through energy efficiency improvements between now and 2010," he says. "We can reduce carbon intensity by substituting clean energy sources for coal combustion by 2020.

Because we have abundant supplies of coal, we can once again burn it in large quantities to produce energy by introducing carbon capture and sequestration technologies by 2030. Right now we can enhance carbon sequestration naturally by planting trees and grasses on marginal farmlands that can be converted to biomass fuel."

Why Sequester Carbon?

Farrell says that if the Kyoto conference recommendations for controlling greenhouse gas emissions are followed, the United States can continue major use of fossil fuels only if we can capture, transport, and dispose of carbon in an economical way. "Right now the technologies are there," he says, "but studies suggest that it would double the cost of electricity from fossil fuel plants." For most Americans, that's too many greenbacks to reduce greenhouse gases.

People will sequester carbon only if a value is placed on this action, Farrell says. "Let's suppose that the government imposed a carbon tax of $50 per ton of carbon discharged. Then it might be economical to capture the carbon and convert it to useful products or dispose of it permanently by injecting it into a geological formation or the ocean. The higher the carbon tax, the more capture and sequestration technologies will be valued."

It will be costly to build a fossil plant, a capture plant, and a natural gas-like infrastructure to pipe half a gigaton of captured carbon gas to special facilities for injection into geological formations or the ocean.

The most economical approach, Farrell says, is to delay the mitigation response for coal-fired power plants because new technology should allow us to capture and sequester carbon emissions more economically in the next three decades. In the meantime, we can switch from high-carbon to lower-carbon or carbon-free fuels and introduce energy efficiency technologies.

Challenges to Carbon Management

One challenge to carbon management is plant and animal biomass. Schaffhauser calls plant biomass "carbon neutral" because, while they give off carbon dioxide when burned, plants absorbed and sequestered the same amount of the greenhouse gas before they were harvested. "Green plants are a gift," Schaffhauser says, "because they provide us with food, fuel, chemicals, building products, and a way to sequester carbon." But biomass can be a large source of carbon dioxide to the atmosphere if large tracts of forest are burned because of drought and demands to clear the land for agriculture and development.

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Landfills are rich sources of methane.

Biomass and other materials disposed of in landfills decay to form landfill gas, which is mostly methane. The release of landfill methane to the air boosts greenhouse gas levels. But landfill gas can be captured and run through gas turbines to produce electricity, turning trash into treasure.

Animal waste is also a challenge to carbon management. According to ORNL's John Sheffield, who is also director of the Joint Institute for Energy and Environment at the University of Tennessee, U.S. farms for raising cattle, poultry, and swine to help feed the world have 1.4 billion tons of wet manure, which annually emits almost 3 million metric tons of methane, a greenhouse gas. Because the United States has about 15% of the world's manure, it is apparent that animal waste worldwide is a significant contributor to greenhouse gas levels.

"Manure is commonly used as a fertilizer," Sheffield says, "but it also is a large, generally untapped, source of energy. Cleverly applied technological solutions could allow farmers to sell manure as a feedstock for producing methane for energy and for making other products. Income from the animal waste feedstock will help farmers offset the costs of controlling pollution from farm chemicals such as fertilizers, pesticides, pathogens, antibiotics, and hormones."

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Burning gas from methane hydrate ice.

Another challenge to carbon management is methane hydrates, which harbor a huge amount of natural gas in the ocean and Arctic permafrost. The problem is that harvesting these hydrates for energy might result in the release of the methane to the atmosphere, raising the greenhouse gas levels enough to change the climate (see "Methane Hydrates: A Carbon Management Challenge" article).

"As a key resource for science and technology, we hope to support DOE's mission of fostering a secure and reliable energy system that is environmentally and economically sustainable," Farrell says. "Our goal is to be DOE's major resource of carbon management science and technology.

"We hope to expand our leadership in energy efficiency R&D by increasing our R&D on distributed energy power, buildings, and transportation. We plan to expand our clean power R&D by increasing our R&D on fuel cells, gas turbines, reciprocating engines, hydrogen production and storage, agricultural biomass genetics, and methane hydrates. Through CSiTE we hope to increase our ability to estimate the potential for terrestrial carbon sequestration. We want to invest in fundamental R&D to advance the development of chemical, biological, and engineering technologies for capturing and sequestering carbon."

David Reichle, who recently retired from ORNL as an associate director, is in charge of helping ORNL leverage its capabilities through partnerships with the other Battelle-managed labs—Brookhaven National Laboratory, Pacific Northwest National Laboratory, and the National Renewable Energy Laboratory. These labs and ORNL have formed a DOE carbon management network. The network will work with core universities and industrial firms to form an R&D consortium. By broadening the network's skill base, its R&D proposals for funding in the area of carbon management should be increasingly competitive.

With such a plan, ORNL hopes to capture a leading role in DOE's research program for managing carbon.

Beginning of Article

Related Web sites

The DOE Center for Research on Enhancing Carbon Sequestion in Terrestrial Ecosystems
ORNL's Buildings Technology Center
ORNL's Center for Global Energy and Environmental Studies
ORNL's Energy Efficiency and Renewable Energy Program
ORNL's Environmental Sciences Division

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