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Some of the mails bouncing



Hi
I have migrated to qmail from sendmail recently. Since migration I have a strange problem, users started complaining they do not receive some of the mails their counter parts send. I am using qmail+vpopmail. I have tried some test mail from hotmail and yahoo. 90 percent of mails from hotmail I have received properly, 10 percent received after a very long delay. Where as fifty percent of mails from yahoo I have received and remaining bounced with following message.
 
Message from  yahoo.com.
>Unable to deliver message to the following address(es).
>
><mrinal@espacetech.com>:
>Sorry, I wasn't able to establish an SMTP connection. (#4.4.1)
>I'm not going to try again; this message has been in the queue too long
 
I have tried from a few other domains and many of the mails bounces with the same message.
My mailserver continuously available and my Internet connection do not seem to have any problem.
 
Can Anyone suggest, what could be wrong?
 
Regards
Mrinal